Journal of Organic Chemistry p. 8171 - 8178 (1995)
Update date:2022-09-26
Topics:
Feldman, Ken S.
Sambandam, Aruna
The biomimetic synthesis of sanguiin H-5 (1) was accomplished through the diastereoselective formation of the crucial biphenyl carbon-carbon bond between galloyl moieties at the O(2) and O(3) positions of an appropriately protected glucose-derived precursor.Furthermore, the β-anomeric galloyl linkage was established with complete stereochemical control.
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