Tetrahedron Letters p. 2245 - 2248 (2001)
Update date:2022-08-04
Topics:
Hussain, Helmi
Kianmehr, Ebrahim
Durst, Tony
Reaction of the azaallyllithiums derived from imines of α-amino esters with benzynes results in the formation of 1,3-dihydroisoindoles and 4-hydroxyisoquinolines via 3+2 and 2+2 cycloadditions, respectively. The initially formed 1-carboethoxy-1,3-dihydroisoindoles rearrange under basic reaction conditions to form 3-(2H)-isoquinolinones.
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