BASE-INDUCED REARRANGEMENT OF 1-TRIMETHYLSILYLPROPARGYL ALCOHOL. GENERATION OF LITHIATED TRIMETHYLSILOXYALLENES AND THEIR REACTIONS

DOI: 10.1016/S0040-4039(01)85575-1

Source and publish data:

Tetrahedron Letters p. 623 - 626 (1980)

Update date:2022-09-26

Topics:

Authors:

Kuwajima, Isao

Kato, Masahiro

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Article abstract of DOI:10.1016/S0040-4039(01)85575-1

Under the effect of butyllithium, 1-trimethylsilylpropagyl alcohol undergoes rearrangement to afford the corresponding trimethylsiloxyallene or its lithiated one, which can be used for the preparation of α,β-unsaturated ketone derivatives.

Full text of DOI:10.1016/S0040-4039(01)85575-1

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