A NEW ALDOL REACTION: A METHOD FOR THE GENERATION OF VINYLOXYBORANES BY THE ACYLATION OF BORON-STABILIZED CARBANIONS

DOI: 10.1246/cl.1981.1193

Source and publish data:

Chemistry Letters p. 1193 - 1196 (1981)

Update date:2022-09-26

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Authors:

Mukaiyama, Teruaki

Murakami, Masahiro

Oriyama, Takeshi

Yamaguchi, Masahiko

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Article abstract of DOI:10.1246/cl.1981.1193

Phenyl-substituted vinyloxyboranes are generated by the acylation of boron-stabilized carbanions with methyl benzoate.Vinyloxyboranes thus generated further react with aldehydes to give the corresponding cross-aldols in good yields.

Full text of DOI:10.1246/cl.1981.1193

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