Alkylaluminum Halide Induced Cyclization of Unsaturated Carbonyl Compounds

DOI: 10.1021/jo00144a027

Source and publish data:

Journal of Organic Chemistry p. 4538 - 4545 (1982)

Update date:2022-07-30

Topics:

Authors:

Snider, Barry B.

Karras, Michael

Price, Robert T.

Rodini, David J.

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Article abstract of DOI:10.1021/jo00144a027

2,6-Dimethyl-5-heptenal (3) and 5-octenal (24) undergo concerted ene reactions with 1 equiv of Me2AlCl and cation-olefin cyclizations with 2 equiv of Me2AlCl, MeAlCl2, or EtAlCl2 to give a zwitterion which reacts to give several products including an ene

Full text of DOI:10.1021/jo00144a027

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