Conversion of Linoleic and Latex Furanoid Acid to Fish C18 Dimethyl Furanoid Isomers

DOI: 10.1039/c39810001110

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1110 - 1111 (1981)

Update date:2022-07-29

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Authors:

Jie, Marcel S. F. Lie Ken

Ahmad, Fasih

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Article abstract of DOI:10.1039/c39810001110

Methyl 9(10),12(13)-dioxo-octadecanoate (derived from methyl linoleate) and 10,13-dioxo-11-methyloctadecanoate (derived from the latex of the rubber plant) were methylated at the methylene carbons located between the two oxo-groups (using MeI, KOH in DMSO) and cyclodehydration furnished a mixture of methyl 9(10),12(13)-epoxy-10(11),11(12)-dimethyloctadeca-9(10),11(12)-dienoates and methyl 10,13-epoxy-11,12-dimethyloctadeca-10,12-dienoate respectively.

Full text of DOI:10.1039/c39810001110

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