Journal of the Chemical Society. Chemical communications p. 1110 - 1111 (1981)
Update date:2022-07-29
Topics:
Jie, Marcel S. F. Lie Ken
Ahmad, Fasih
Methyl 9(10),12(13)-dioxo-octadecanoate (derived from methyl linoleate) and 10,13-dioxo-11-methyloctadecanoate (derived from the latex of the rubber plant) were methylated at the methylene carbons located between the two oxo-groups (using MeI, KOH in DMSO) and cyclodehydration furnished a mixture of methyl 9(10),12(13)-epoxy-10(11),11(12)-dimethyloctadeca-9(10),11(12)-dienoates and methyl 10,13-epoxy-11,12-dimethyloctadeca-10,12-dienoate respectively.
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