
Journal of Organometallic Chemistry p. 153 - 156 (1971)
Update date:2022-08-04
Topics:
S. Washburne, Stephen
R. Peterson Jr., William
The reaction of sodium azide with chlorosilanes in hexamethylphosphoric triamide or dimethylformamide at room temperature affords a high yield preparation of silyl azides, e.g. Me3SiN3,Me2Si(N3)2, PhMeSi(N3)2 and Ph2Si(N3)2. For characterization, the azides may be converted to silyphosphiimies, R3Si-N=PPh3.
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