Chemistry of substituted quinolinones. V. Synthesis and use of quinolinylphosphazenes in amination of 8-methylquinoline

Article abstract of DOI:10.1080/10426500008082406

2,4-Dihalo-8-methylquinolines 2,3 have been prepared and subjected to azidation and hydrazination reactions showing interesting regioselective properties to give compounds 4-10. The targeted aminoquiolines 13, 14, 15, 17, 19, 22 and 23 were obtained via hydrolysis of their corresponding phosphazenes 11, 12, 16, 18, 20 and 21, respectively. These phosphazenes have been preliminary obtained by condensation of azido and/or tetrazoloquinolines 4, 5, 6, 10, 18 and 22, with triphenylphosphine in either boiling benzene or 1,2-dichlorobenzene.

Full text of DOI:10.1080/10426500008082406

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Phosphorus, Sulfur, and
Silicon and the Related
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Chemistry of Substituted
Quinolinones. v.
Synthesis and Use of
Quinolinylphosphazenes
in Amination of 8-
Methylquinoline
M. M. Ismail a , M. Abass a & M. M. Hassan a
a Department of Chemistry, Faculty of
Education, Ain Shams University, Roxy Cairo,
11711, Egypt
Version of record first published: 03 Jan 2007.
To cite this article: M. M. Ismail , M. Abass & M. M. Hassan (2000): Chemistry
of Substituted Quinolinones. v. Synthesis and Use of Quinolinylphosphazenes in
Amination of 8-Methylquinoline, Phosphorus, Sulfur, and Silicon and the Related
Elements, 167:1, 275-288
To link to this article: http://dx.doi.org/10.1080/10426500008082406
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