Catalysis Communications p. 584 - 587 (2010)
Update date:2022-08-03
Topics:
Jiang, He-yan
Chen, Hua
Li, Rui-xiang
In this communication, we describe the highly enantioselective heterogeneous hydrogenation of aromatic ketones catalyzed by Ph3P stabilized Ru/γ-Al2O3, and modified by chiral diamines derived from cinchona alkaloids. A broad range of aromatic ketones over this catalyst can be hydrogenated to the corresponding alcohols with impressive enantioselectivity.
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