Radically polymerizable pseudorotaxane monomers: Versatile building units for side chain polyrotaxane synthesis

DOI: 10.1246/cl.1999.111

Source and publish data:

Chemistry Letters p. 111 - 112 (1999)

Update date:2022-09-26

Topics:

Authors:

Takata, Toshikazu

Kawasaki, Hiroaki

Asai, Satoko

Kihara, Nobuhiro

Furusho, Yoshio

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Article abstract of DOI:10.1246/cl.1999.111

Side chain polyrotaxanes were synthesized from radically polymerizable pseudorotaxane monomers (DB24C8·1) which were composed of secondary ammonium salts having (meth)acryl group at one end and bulky stopper at the other end (1a and 1b) and dibenzo-24-crown-8 (DB24C8). Both radical polymerization of DB24C8·1 and copolymerization of DB24C8·1a with styrene afforded corresponding polymers having rotaxane moieties in the side chains (2a, 2b, and 3).

Full text of DOI:10.1246/cl.1999.111

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