Journal of the American Chemical Society p. 8714 - 8715 (2003)
Update date:2022-09-26
Topics:
Comely, Alex C.
Eelkema, Rienk
Minnaard, Adriaan J.
Feringa, Ben L.
A novel integrated bio- and chemocatalytic approach to the de novo catalytic asymmetric synthesis of saccharides has been developed. Acetoxypyranones obtained enantiopure by enzymatic resolution have been shown to undergo highly stereoselective palladium-catalyzed formal O-glycoside bond formation. The combination of these protocols can be applied to the iterative asymmetric catalytic synthesis of saccharides. Copyright
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