Journal of Carbohydrate Chemistry p. 121 - 143 (2001)
Update date:2022-07-29
Topics:
Akai, Shoji
Kajihara, Yasuhiro
Nagashima, Yasuhiko
Kamei, Masugu
Arai, Junko
Bito, Masami
Sato, Ken-Ichi
New styryl monomers containing β-D-mannopyranose, 2-acetamido-2-deoxy-β-D-mannopyranose, 2-deoxy-2-fluoro-β-D-mannopyranose, and 2-deoxy-β-D-arabino-hexopyranose on their side chains, were efficiently synthesized as a new class of a potent inhibitor resistant to exo-α-mannosidase digestion. The binding affinity of the carbohydrate polymers obtained from those mannopyranosyl styryl monomers by radical polymerization with Concanavalin A were evaluated. A binding assay indicated that the multivalency effect and the affinity enhancement attained by modification at the C-2 position of the β-D-mannopyranoside residue resulted in the.
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