Direct Oxidative Addition-Reductive Elimination Reactions Between trans- and or trans- (M = Rh or Ir, L = tertiary phosphine)

DOI: 10.1039/DT9810000319

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 319 - 321 (1981)

Update date:2022-08-03

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Authors:

Al-Jibori, Subhi

Crocker, Christopher

Shaw, Bernard L.

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Article abstract of DOI:10.1039/DT9810000319

Complexes of the type trans- and .M = Rh or Ir, L = PMe2Ph or PEt2Ph, have been shown to react with each other, presumably by a double chloro-bridged intermediate, and undergo rapid oxidative addition-reductive elimination; phosphine exchange is much slower.Similar results were obtained when trans- was treated with trans-, M = Rh or Ir, for which rapid and complete conversion into trans- and occured. (31)P NMR data are given.

Full text of DOI:10.1039/DT9810000319

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