Journal of the Chemical Society. Chemical communications p. 542 - 543 (1983)
Update date:2022-09-26
Topics:
Grenouillet, Pierre
Neibecker, Denis
Tkatchenko, Igor
Basic phosphines, especially tributylphosphine, when added in 1:1 ratio to cationic allylpalladium complexes, allow the selective co-dimerisation of 1,3-dienes and acrylic esters to linear, unsaturated esters, presumably owing to the inducement of an η3-η1 shift of the allyl ligands by the phosphines.
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