Co-dimerisation of 1,3-Dienes and Acrylic Esters catalysed by Cationic Allylpalladium Complexes: the Role of Phosphines

DOI: 10.1039/c39830000542

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 542 - 543 (1983)

Update date:2022-09-26

Topics:

Authors:

Grenouillet, Pierre

Neibecker, Denis

Tkatchenko, Igor

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39830000542

Basic phosphines, especially tributylphosphine, when added in 1:1 ratio to cationic allylpalladium complexes, allow the selective co-dimerisation of 1,3-dienes and acrylic esters to linear, unsaturated esters, presumably owing to the inducement of an η³-η¹ shift of the allyl ligands by the phosphines.

Full text of DOI:10.1039/c39830000542

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:bis(triphenylphosphine){(1,2,3-η)-2-methyl-2-propenyl}palladium tetrafluoroborate

Cas No:36543-50-7

R&D Labs maybe for 36543-50-7

Zhejiang Kente Chemical Co.,Ltd.

Contact:86-0576-87651912

Address:No.7, Fengxi West Road, Modern Industrial Zone
Linyi VIHO Chemical Co.,Ltd

Contact:86-15588110016

Address:LINYI CITY,SHANDONG PROVINCE,CHINA
SHANGHAI T&W PHARMACEUTICAL CO., LTD.

website:http://www.trustwe.com

Contact:+86-21-61551413

Address:601, No. 1, 2277 Nong, Zu Chongzhi Road, Zhangjiang Hightech. Park, Pudong
Taixing Shenfeng Chemical Co., Ltd.

Contact:+86-523-87117033, 87117666

Address:4# Yinsanlu, Huangqiao town, Taixing, Jiangsu, China.
Hangzhou innopharma technology Co,.Ltd.(expird)

Contact:+86-13388601988

Address:Room845,lixin building, moganshan road, hangzhou, china

Relevant to this article

The structures of six antifungal oligoglycosides, stichlorosides A₁, A₂, B₁, B₂, C₁, and C₂, from the sea cucumber Stichopus chloronotus (Brandt)

Doi:10.1248/cpb.29.2387
(1981)
A macroporous polymer-supported cyclic anhydride for efficient sequestration of amines

Doi:10.1016/j.tetlet.2008.08.038
(2008)
Doi:10.1021/jo00799a023
(1972)
5-Substituted 2-alkyl- and 2-arylsulfonyliminohexahydro-1,3,5-triazines

Doi:10.1023/A:1011369409476
(2001)
Selective: N-formylation/N-methylation of amines and N-formylation of amides and carbamates with carbon dioxide and hydrosilanes: Promotion of the basic counter anions of the zinc catalyst

Doi:10.1039/d0gc02890h
(2020)
Triazole linked picolylimine conjugate of calix[6]arene as a sequential sensor for La³⁺ followed by F^-

Doi:10.1021/ol300919h
(2012)

Article Doi