Co-dimerisation of 1,3-Dienes and Acrylic Esters catalysed by Cationic Allylpalladium Complexes: the Role of Phosphines

DOI: 10.1039/c39830000542

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 542 - 543 (1983)

Update date:2022-09-26

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Authors:

Grenouillet, Pierre

Neibecker, Denis

Tkatchenko, Igor

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Article abstract of DOI:10.1039/c39830000542

Basic phosphines, especially tributylphosphine, when added in 1:1 ratio to cationic allylpalladium complexes, allow the selective co-dimerisation of 1,3-dienes and acrylic esters to linear, unsaturated esters, presumably owing to the inducement of an η³-η¹ shift of the allyl ligands by the phosphines.

Full text of DOI:10.1039/c39830000542

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