Journal of the Chemical Society. Perkin transactions I p. 1431 - 1435 (1980)
Update date:2022-08-03
Topics:
Busby, Reginald E.
Khan, Mohammad A.
Khan, Mohammad R.
Parrick, John
Shaw, C. J. Granville
The vapor-phase reactions of imidazolines and anils with chloroform at 550 deg C are compared with their liquid-phase reactions in the presence of hexachloroacetone and base or upon thermolysis with trichloroacetate ion.In the vapour-phase reactions imidazolines, unlike imidazoles, gave non-chlorinated pyrimidines, and 1-methyl-imidazole gave 2-cyanopyrrole and the four 3-chlorocyanopyridines.
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