Bulletin of the Chemical Society of Japan p. 164 - 170 (1989)
Update date:2022-07-29
Topics:
Otsubo, Tetsuo
Aso, Yoshio
Ogura, Fumio
Misumi, Soichi
Kawamoto, Atsushi
Tanaka, Jiro
The title compound was synthesized in a similar manner to a simple access to triple-layered <2.2><2.2>paracyclophane.Its structure was elucidated by X-ray crystallographic analysis.The outer naphthalene rings are bent into a boat form and the inner naphthalene ring is bent into a twist form.These naphthalenes are stacked in layers within van der Waals contact.Therefore, there is a strong transannular ?-electronic interaction between them, which brings about characteristic bathochromism, hyperchromism, and broadening in the electronic spectrum.These effects are more prominent than those of the double-layered homologue.
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