Syntheses of Acyclo-C-nucleosides by Ring Transformation of 2(3)-Formyl-glycals

DOI: 10.1002/prac.19983400407

Source and publish data:

Advanced Synthesis and Catalysis p. 334 - 340 (1998)

Update date:2022-08-03

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Authors:

Rudloff, Ivo

Peseke, Klaus

Reinke, Helmut

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Article abstract of DOI:10.1002/prac.19983400407

The 2(3)-formyl-glycals 2, 4, 6 react with hydrazine hydrate to furnish the C-(1H-pyrazol-3-yl)alditoles 7, 8, 9. Treatment of 2, 4, 6 with cyanoacetamide provides the 2(3)-(2-aminocarbonyl-2-cyano-vinyl)-1,5(2,6)-anhydro-2(3)-deoxy-hex-1-enitols 10, 13,

Full text of DOI:10.1002/prac.19983400407

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