Bulletin of the Chemical Society of Japan p. 1740 - 1742 (1994)
Update date:2022-09-26
Topics:
Yanagi, Ryouta
Matui, Chinami
Chinda, Mituru
Yamamoto, Yasushi
The stereoisomers of 2-butanone O-trimethylsilyloxime were observed as separate peaks, the intensity ratio being 1:3, by high resolution GC equipped with a capillary column. The peak with intensity 3 was assigned to the Z isomer of oxime bond and the intensity ratio corresponded to the stereoisomer ratio of 2-butanone oxime. Silanes including plural oxime groups also gave separate stereoisomer peaks corresponding to the isomer ratio of 2-butanone oxime.
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