ORGANOBORN COMPOUNDS. CDI. CHLORO-ALLYLLIC REARRANGEMENT OF 7-CHLOROMETHYL-3-ALLYL-3-BORABICYCLONON-6-ENE TO 6-CHLORO-7-METHYLENE-3-ALLYL-3-BORABICYCLONONANE. SYNTHESIS OF 4-CHLORO-1-BORAADAMANTANE COMPLEXES

Article abstract of DOI:10.1016/S0022-328X(00)98646-7

7-Chloromethyl-3-allyl-3-borabicyclo<3.3.1>non-6-ene(VI) was found to isomerise at 120-130 deg C to 6-chloro-7-methylene-3-allyl-3-borabicyclo<3.3.1>nonane (VII), the ratio between VI and VII in an equilibrium mixture thereby formed being 2:3.Hydroboratio