Copper-Mediated Hydroxylation of an Arene: Kinetics and Mechanism of the Reaction of a Dicopper(II) m-Xylyl-Containing Complex with H2O2 To Yield a Phenoxodicopper(II) Complex

DOI: 10.1021/ja00223a020

Source and publish data:

Journal of the American Chemical Society p. 5020 - 5024 (1988)

Update date:2022-07-29

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Authors:

Cruse, Richard W.

Kaderli, Susan

Meyer, Charles J.

Zuberbuehler, Andreas D.

Karlin, Kenneth D.

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Article abstract of DOI:10.1021/ja00223a020

The kinetics and mechanism of the hydroxylation by H2O2 of a dicopper(II) complex ⁴⁺ (5) to the phenoxo and hydroxo doubly bridged product ²⁺ (3) are reported.In 50percent H2O/N,N-dimethylformamide the reactio

Full text of DOI:10.1021/ja00223a020

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