Bulletin of the Chemical Society of Japan p. 2379 - 2384 (1995)
Update date:2022-08-04
Topics:
Kusama, Hiroyuki
Narasaka, Koichi
The intermolecular Friedel-Crafts acylation of aromatic compounds (such as toluene, m-xylene, and anisole) with various acid chlorides proceeds by using a catalytic amount of bromopentacarbonylrhenium(I) to afford aryl ketones.Intramolecular acylation is also catalyzed by the above-mentioned catalyst to give indanone and tetralone derivatives.
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