Tetrahedron Letters p. 6136 - 6141 (2015)
Update date:2022-08-05
Topics:
Zhang, Qian
Wang, Ying
Yang, Tingting
Li, Li
Li, Dong
A palladium-catalyzed ortho-C-H-benzoxylation of 2-arylpyridines using iodobenzene dibenzoates has been developed. The reaction employed the stable and easily accessible hypervalent iodine reagents as both benzoxylate source and oxidant which made the protocol simple and facile. It showed high regioselectivity and good functional group tolerance, and gave the mono-benzoxylation products in moderate to excellent yields.
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