Chemistry Letters p. 785 - 786 (1998)
Update date:2022-07-30
Topics:
Nishimae, Shinji
Inoue, Rie
Shinokubo, Hiroshi
Oshima, Koichiro
Treatment of 2-alkynylphenol with an alkyl Grignard reagent in the presence of a catalytic amount of manganese(II) chloride provided 2-(2-alkyl-1-alkenyl)phenol in good yield. Alkylmagnesation proceeded with high regio-and stereoselectivities.
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