Manganese(II) chloride-catalyzed alkylmagnesation of 2-alkynylphenol

DOI: 10.1246/cl.1998.785

Source and publish data:

Chemistry Letters p. 785 - 786 (1998)

Update date:2022-07-30

Topics:

Authors:

Nishimae, Shinji

Inoue, Rie

Shinokubo, Hiroshi

Oshima, Koichiro

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Article abstract of DOI:10.1246/cl.1998.785

Treatment of 2-alkynylphenol with an alkyl Grignard reagent in the presence of a catalytic amount of manganese(II) chloride provided 2-(2-alkyl-1-alkenyl)phenol in good yield. Alkylmagnesation proceeded with high regio-and stereoselectivities.

Full text of DOI:10.1246/cl.1998.785

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