Journal of Organometallic Chemistry p. 102 - 108 (2001)
Update date:2022-07-31
Topics:
Zhang, Yongqiang
Cervantes-Lee, Francisco
Pannell, Keith H.
Photochemical irradiation of the new bimetallic disilyliron complexes (SiMe2)[(η5-C5H4)Fe(CO) 2SiMe2SiMe2R]2, R=Me, Ph, results in silylene elimination chemistry, as observed for the mono-metallic analogs, resulting in the formation of complexes (SiMe2)[(η5-C5H4)Fe(CO) 2SiMe2R]2. The intermediate silyl(silylene) complexes can be intercepted with HMPA. Apart from a very reactive minor product that we have been unable to identify at this time, the proximity of the two transition metal centers has little impact upon the observed chemistry.
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