Sequential biocatalytic resolution of (±)-trans-cyclohexane-1,2-diamine. Chemoenzymatic synthesis of an optically active polyamine

DOI: 10.1039/CC9960002471

Source and publish data:

Chemical Communications p. 2471 - 2472 (1996)

Update date:2022-08-03

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Authors:

Alfonso, Ignacio

Astorga, Covadonga

Rebolledo, Francisca

Gotor, Vicente

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Article abstract of DOI:10.1039/CC9960002471

Candida antarctica lipase-catalysed double monoaminolysis of dimethyl malonate by (±)-trans-cyclohexane-1,2-diamine allows the sequential resolution of the latter compound, affording an enantiopure bis(amidoester), (R,R)-3, which is subsequently transformed into an optically active polyamine, (R,R)-9.

Full text of DOI:10.1039/CC9960002471

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