Tetrahedron Letters p. 7587 - 7590 (2001)
Update date:2022-08-05
Topics:
Hirasawa, Hideaki
Taniguchi, Takahiko
Ogasawara, Kunio
The intramolecular ene reaction of the 1,6-diene on a bicyclo[3.2.1]octane framework proceeds in a highly diastereoselective manner to form a trisubstituted pyrrolidine on the pyran ring in excellent yield. Its stereochemistry has been determined unambiguously by converting it into the known compound serving as a key intermediate of (-)-kainic acid.
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