ACYL MIGRATION IN 2-SUBSTITUTED-2-ACYLPROPYL RADICALS. THE REACTION OF ORGANOCOBALOXIMES AS MIMICRIES OF COENZYME-B12

DOI: 10.1016/S0040-4039(01)90472-1

Source and publish data:

Tetrahedron Letters p. 1899 - 1902 (1981)

Update date:2022-08-04

Topics:

Authors:

Okabe, Masami

Osawa, Tsutomu

Tada, Masaru

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Article abstract of DOI:10.1016/S0040-4039(01)90472-1

Radical cleavage of the carbon-cobalt bond of 2-acetyl-2-methoxy-carbonylpropyl cobaloxime (1) and 2-benzoyl-2-phenylpropyl cobaloxime (5) gives the enones wich are formed by the 1,2-migration of acyl-group.

Full text of DOI:10.1016/S0040-4039(01)90472-1

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