Journal of the American Chemical Society p. 5003 - 5008 (1987)
Update date:2022-09-26
Topics:
Rak, Stanton F.
Lapin, Stephen C.
Falvey, Daniel E.
Schuster, Gary B.
The properties of the 2,7-dihalofluorenylidenes (Cl, Br, I) were examined by laser and EPR spectroscopy and by conventional chemical analyses.Their reactions with alcohols and olefins were studied.No evidence was found for the operation of a heavy atom effect in their reaction with methyl alcohol.Analysis of the kinetic and product results indicates an energy gap between the triplet (ground state) and the singlet for the three dihalofluorenylidenes of 4.2 +/- 0.5 kcal/mol, ca. twice the value of fluorenylidene itself.
View MoreShangHai Original Economy-Trade Develop Co.,Ltd.,
Contact:86-21-68552131
Address:shanghai
Wuxi D-Stone International Co., Ltd.
Contact:+86-510-82740567
Address:21F Hengtong Int'l Centre, 215Zhongshan Road, Wuxi, Jiangsu,China
Longhui qunfeng Chemical Co., Ltd
Contact:86-731-82173407
Address:South-east Industrial Park, Longhui County, Hunan Province, China
SHIJIAZHUANG CHENSHI IMPORT AND EXPORT CO.,LTD
Contact:+86-311-89871056
Address:RM2017 BUILDING CTIANSHAN GALAXY PLAZA,NO168 CHANGJIANG ROAD,GAOXIN DISTRICT,SHIJIAZHUANG CITY, HEBEI,CHINA
Contact:+65 9658 0999
Address:26 Sin Ming Lane, Midview City, #05-118, Singapore 573971
Doi:10.1016/S0040-4039(01)01833-0
(2001)Doi:10.1016/S0022-328X(00)84883-4
(1978)Doi:10.1071/CH02253
(2003)Doi:10.1021/acs.orglett.8b00681
(2018)Doi:10.1021/op5003424
(2015)Doi:10.1021/bi00696a009
(1975)
