Journal of the American Chemical Society p. 5003 - 5008 (1987)
Update date:2022-09-26
Topics:
Rak, Stanton F.
Lapin, Stephen C.
Falvey, Daniel E.
Schuster, Gary B.
The properties of the 2,7-dihalofluorenylidenes (Cl, Br, I) were examined by laser and EPR spectroscopy and by conventional chemical analyses.Their reactions with alcohols and olefins were studied.No evidence was found for the operation of a heavy atom effect in their reaction with methyl alcohol.Analysis of the kinetic and product results indicates an energy gap between the triplet (ground state) and the singlet for the three dihalofluorenylidenes of 4.2 +/- 0.5 kcal/mol, ca. twice the value of fluorenylidene itself.
View MoreTianjin Emulsion Science&Technology Development Co.,Ltd
Contact:13901380442
Address:Vake Garden New Town New Yi Bai Road Beichen District Tianjin,China
TIANJIN FESTO CHEMICAL CO.,LTD(expird)
Contact:86-22-25814570
Address:No.12th,5th Ave.,TEDA,Tianjin,China
Jinhua Haoyuan Chemical CO., LTD(expird)
Contact:86-579-82465583
Address:Jinhua,Zhejiang
Jiangsu Hualun Chemical Industry Co., Ltd
website:http://www.hualunchem.com
Contact:+86-0514-86464168 86507985
Address:39# Middle Renmin Road, Dinghuo Town
suzhou chukai pharmateach co,.ltd
website:http://www.chukaipharma.com/
Contact:86-512-888125066
Address:Building 3, Wujiang Scientific Innovation Park, 2358 Changan Rd, Wujiang 215200, Jiangsu Province, P. R. China
Doi:10.1016/S0040-4039(01)01833-0
(2001)Doi:10.1016/S0022-328X(00)84883-4
(1978)Doi:10.1071/CH02253
(2003)Doi:10.1021/acs.orglett.8b00681
(2018)Doi:10.1021/op5003424
(2015)Doi:10.1021/bi00696a009
(1975)
