Organic Letters p. 2338 - 2341 (2018)
Update date:2022-09-26
Topics:
Sedgwick, Daniel M.
López, Inés
Román, Raquel
Kobayashi, Nanako
Okoromoba, Otome E.
Xu, Bo
Hammond, Gerald B.
Barrio, Pablo
Fustero, Santos
A simple, user-friendly, metal-free protocol for the regioselective anti-Markovnikov hydrofluorination of olefins using readily available and inexpensive reagents has been developed. This new approach displays a broader scope than previously reported methodologies and has been applied to the late-stage fluorination of a complex molecule, giving rise to a fluorosteroid derivative. The stereochemistry of the process has also been studied in some detail.
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