Stereochemistry of Hydrolysis at an Acyclic Phosphoryl Centre leading to an Achiral Phosphorus Acid

DOI: 10.1039/c39840000251

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Journal of the Chemical Society. Chemical communications p. 251 - 252 (1984)

Update date:2022-07-31

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Authors:

Trippett, Stuart

White, Colin L.

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Article abstract of DOI:10.1039/c39840000251

Alkaline hydrolysis of S_P-methyl methylphenylphosphinate in 60percent H2¹⁸O has been shown to involve predominant (>90percent) inversion of configuration at phosphorus; esterification of the resulting acid with the diazocompounds (2)

Full text of DOI:10.1039/c39840000251

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