Acidic Isomerization of Vicinally Substituted (cis)-Acceptor-Donor Cyclopropanes via an Open Ring Mechanism

DOI: 10.1016/S0040-4039(00)73037-1

Source and publish data:

Tetrahedron Letters p. 2017 - 2020 (1994)

Update date:2022-08-03

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Authors:

Dechoux, Luc

Doris, Eric

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Article abstract of DOI:10.1016/S0040-4039(00)73037-1

Many (cis)-cyclopropanes bearing 1-electronwithdrawing and 2-hydroxymethylene groups were synthesized under mild acidic conditions to afford the corresponding trans isomers.The mechanism is reported.

Full text of DOI:10.1016/S0040-4039(00)73037-1

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