Alteration of electronic effect causes change in rate determining step: Oxovanadium(IV)–salen catalyzed sulfoxidation of phenylmercaptoacetic acids by hydrogen peroxide

DOI: 10.1016/j.poly.2019.114172

Source and publish data:

Polyhedron (2020)

Update date:2022-08-02

Topics:

Authors:

Kavitha Kavitha

Subramaniam

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Article abstract of DOI:10.1016/j.poly.2019.114172

Sulfoxidation of a series of phenylmercaptoacetic acids (PMAA) by hydrogen peroxide catalysed by oxovanadium(IV)–salen complexes has been carried out spectrophotometrically in 100% acetonitrile medium. The formation and involvement of hydroperoxovanadium(

Full text of DOI:10.1016/j.poly.2019.114172

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