Diastereoselective [2,3] Wittig rearrangement of carbohydrate-derived tertiary allylic ethers. 1. Synthesis of the C11-C18 subunit of herbimycin a fromD-glucose

DOI: 10.1016/0040-4039(93)89002-8

Source and publish data:

Tetrahedron Letters p. 749 - 752 (1993)

Update date:2022-07-31

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Authors:

Eshelman, Jill E.

Epps, Janet L.

Kallmerten, James

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Article abstract of DOI:10.1016/0040-4039(93)89002-8

Reductive fragmentation of the D-glucose derived iodopyranose 7 and diastereoselective [2,3] Wittig rearrangement of the resulting tertiary allylic ether affords trisubstituted olefin 19, comprising the C₁₁-C₁₈ segment of the benzoqu

Full text of DOI:10.1016/0040-4039(93)89002-8

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