Peptide Synthesis in Aqueous Solution. V. Properties and Reactivities of (p-Hydroxyphenyl)benzylmethylsulfonium Salts for Direct Benzyl Esterification of N-Acylpeptides

DOI: 10.1246/bcsj.69.1099

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1099 - 1106 (1996)

Update date:2022-08-05

Topics: -Aqueous solution -peptide synthesis -properties

Authors:

Nakata, Takashi

Nakatani, Masaru

Takahashi, Masatoshi

Okai, Jiro

Kawaoka, Yoshiaki

Kouge, Katsushige

Okai, Hideo

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Article abstract of DOI:10.1246/bcsj.69.1099

Some (p-hydroxyphenyl)benzylmethylsulfonium salts were prepared. These compounds generated a benzyl cation and converted not only N-acylamino acids but also N-acylpeptides into their corresponding benzyl esters without causing the racemization.

Full text of DOI:10.1246/bcsj.69.1099

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