Synthese de N-alkyl tetrahydro-2,3,6,7 azepines et de N-alkyl hexahydro-1,2,3,4,7,8 azocines a partir d'ω-monoalkylaminoallyltrimethylsilanes par processus d'aminomethylation-desilylation intramoleculaire

DOI: 10.1016/0022-328X(90)80253-V

Source and publish data:

Journal of Organometallic Chemistry p. 19 - 28 (1990)

Update date:2022-09-26

Topics:

Authors:

Guyot, B.

Pornet, J.

Miginiac, L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(90)80253-V

In acidic medium, the ω-monoalkylaminoallyltrimethylsilanes RNH(CH2)nCH-(SiMe3)CH=CH2 (n=2, 3) regiospecifically react with formaldehyde, by an intramolecular process, to give alkenyl nitrogen-containing heterocycles, such as N-alkyl-2,3,6,7-tetrahydroaze

Full text of DOI:10.1016/0022-328X(90)80253-V

Products guided by the article

Product name:4-Penten-1-ol, 3-(trimethylsilyl)-, 4-methylbenzenesulfonate

Cas No:403985-14-8

R&D Labs maybe for 403985-14-8

Shantou Baokang Pharmaceutical Co., Ltd.

Contact:+86-754-88873487

Address:5/F B Block Huangshan Bldg Huangshan Rd Shantou
Hangzhou jls Flame Retardants Chemical Co.,Ltd

Contact:+86-571-87250387/87250386

Address:MOGANSHAN RODA 1418# SHANGCHENG INDUSTRIAL PARK
Huangshan Honghui Pharm Technology Co., Ltd.(expird)

website:http://www.honghuichem.com

Contact:18855958372

Address:Qingshan Wan No.1,Nanyuan Kou,SheXian Huangshan City,Anhui Province
Beijing Mashi Fine Chemical Co.,Ltd.

Contact:+86-10-61271592

Address:Room 506, Section B, Kaichi Mansion, Industrial Development
Taiwan Surfactant Corp.

Contact:886 2 2541 0022

Address:8 Fl., No. 11, Sec. 1, Chung Shan North Rd., Taipei, Taiwan R.O.C.

Relevant to this article

Novel Erythromycin Derivatives with aryl Groups Tethered to the C-6 Position Are Potent Protein Synthesis Inhibitors and Active against Multidrug-Resistant Respiratory Pathogens

Doi:10.1021/jm0102349
(2001)
Efficient and practical protection of the catechol residue of 3,4-dihydroxy-phenylalanine (DOPA) derivative as acetonide

Doi:10.1055/s-2008-1032164
(2008)
The stereochemistry of electrolysis and samarium diiodide-induced cyclization between carbonyl and enone system in inter- and intramolecular coupling

Doi:10.3987/com-06-s(k)45
(2007)
Doi:10.1021/ja01589a043
(1956)
Doi:10.1016/S0022-1139(00)80506-0
(1986)
Doi:10.1007/BF00480583
()

Article Doi