Allylic tin(IV)-tin(II) chloride-acetonitrile as a novel system for allylation of carbonyls or imines

DOI: 10.1016/0040-4039(96)01285-3

Source and publish data:

Tetrahedron Letters p. 5951 - 5954 (1996)

Update date:2022-08-05

Topics:

Authors:

Yasuda, Makoto

Sugawa, Yoshihiro

Yamamoto, Akihiro

Shibata, Ikuya

Baba, Akio

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Article abstract of DOI:10.1016/0040-4039(96)01285-3

Effective allylation of aldehydes, ketones and imines was accomplished by allylic tributyltins 1 in the presence of SnCl₂ in an acetonitrile solution. In this reaction system, Sn(IV)-Sn(II) transmetallation must play a key role, generating the

Full text of DOI:10.1016/0040-4039(96)01285-3

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