Diastereoselective synthesis of chiral clusters from the reaction of chiral (propargyl alcohol)Co2(CO)6 with triphenylphosphine

DOI: 10.1021/om00104a044

Source and publish data:

Organometallics p. 554 - 556 (1989)

Update date:2022-08-05

Topics:

Authors:

Bradley, David H.

Khan, Masood A.

Nicholas, Kenneth M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/om00104a044

Dicobalt hexacarbonyl complexes of chiral (racemic) propargylic alcohols 1 react with PPh₃ to form the diastereomeric complexes [R¹C≡CCH(OH)R²]Co₂-(CO) ₅PPh₃ (2) with diastereomeric excesse

Full text of DOI:10.1021/om00104a044

Products guided by the article

Product name:HCCCH(OH)(CH₃)Co₂(CO)6

Cas No:40687-04-5

R&D Labs maybe for 40687-04-5

Shanghai Standard Biotech Co., Ltd.

Contact:+86-18502101150

Address:Room 103, Building 2nd, NO.720, Cailun Road , Pudong District, Shanghai, China
Dezhou Longteng Chemical Co., Ltd.

website:http://www.sodium-methoxide.cn/

Contact:0086-18866052283

Address:Xinhua Industrial Zone, Dezhou City, Shandong Province, China
Shanghai UCHEM Inc.

Contact:+86-21-56338808

Address:799 Dunhuang Road, Putuo
Hebei Lead Bio-Chemicals Co., Ltd.

website:http://www.ldbiochem.com

Contact:+86-311-87826503

Address:481, Heping West Road, Shijiazhuang,China
Qingzhou Baibang import and export co.,Ltd

Contact:+86-536-3265899

Address:No.338, Tuoshan Road

Relevant to this article

Organic triplet emissions of arylacetylide moieties harnessed through coordination to [Au(PCy₃)]⁺. Effect of molecular structure upon photoluminescent properties

Doi:10.1021/ja0209417
(2002)
Chemical, electrochemical, and structural aspects of the ruthenium complexes Ru(η-arene)Cl₂(P) (where arene = benzene, [2.2]paracyclophane and P = triphenylphosphine, rac-[2.2]paracyclophanylphosphine)

Doi:10.1021/om010763a
(2002)
1H-Pyrazole-1-carboxamidine Hydrochloride: An Attractive Reagent for Guanylation of Amines and Its Application to Peptide Synthesis

Doi:10.1021/jo00034a059
(1992)
Sulfonamidation of halogen-substituted electrophiles with N-(2,2,2-trichloroethyl)arenesulfonamides

Doi:10.1134/S1070428017060021
(2017)
Chelating P,N versus P,P ligands: Differing reactivity of donor-stabilized pt(η²-PhC≡CPh) complexes toward diphenylacetylene

Doi:10.1021/om010924a
(2002)
Doi:10.1002/macp.1973.021720103
(1973)

Article Doi