Diastereoselective synthesis of chiral clusters from the reaction of chiral (propargyl alcohol)Co2(CO)6 with triphenylphosphine

DOI: 10.1021/om00104a044

Source and publish data:

Organometallics p. 554 - 556 (1989)

Update date:2022-08-05

Topics:

Authors:

Bradley, David H.

Khan, Masood A.

Nicholas, Kenneth M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/om00104a044

Dicobalt hexacarbonyl complexes of chiral (racemic) propargylic alcohols 1 react with PPh₃ to form the diastereomeric complexes [R¹C≡CCH(OH)R²]Co₂-(CO) ₅PPh₃ (2) with diastereomeric excesse

Full text of DOI:10.1021/om00104a044

Products guided by the article

Product name:HCCCH(OH)(CH₃)Co₂(CO)6

Cas No:40687-04-5

R&D Labs maybe for 40687-04-5

Kraeber & Co GmbH

Contact:+49-4101-3053-0

Address:Waldhofstrasse 14 ,25474 Ellerbek Germany
Exploiter Molybdenum Co.,Ltd

Contact:86-379-63338609

Address:Jiudian Village,Deting Town,Song County,Luoyang
Wuhan Shengmao Corp

website:http://www.shengmaochem.com

Contact:86-27-82853423, 82819281

Address:Rm 202, A Unit Huaqiao Building No. 2, Lihuangpi Road, Wuhan, China
Nanjing Norris Pharm Technology Co., Ltd.

Contact:+86-13901585132

Address:2 Qiande Road, Jiangning sciencepark Hi-Tech Zone, Nanjing, P.R.China
SHANGHAI BIOSUNDRUG CO.,LTD.

Contact:86-21-34622192，13917187091，21-34622765

Address:No. 500 Caobao Road Shanghai P.R China

Relevant to this article

Organic triplet emissions of arylacetylide moieties harnessed through coordination to [Au(PCy₃)]⁺. Effect of molecular structure upon photoluminescent properties

Doi:10.1021/ja0209417
(2002)
Chemical, electrochemical, and structural aspects of the ruthenium complexes Ru(η-arene)Cl₂(P) (where arene = benzene, [2.2]paracyclophane and P = triphenylphosphine, rac-[2.2]paracyclophanylphosphine)

Doi:10.1021/om010763a
(2002)
1H-Pyrazole-1-carboxamidine Hydrochloride: An Attractive Reagent for Guanylation of Amines and Its Application to Peptide Synthesis

Doi:10.1021/jo00034a059
(1992)
Sulfonamidation of halogen-substituted electrophiles with N-(2,2,2-trichloroethyl)arenesulfonamides

Doi:10.1134/S1070428017060021
(2017)
Chelating P,N versus P,P ligands: Differing reactivity of donor-stabilized pt(η²-PhC≡CPh) complexes toward diphenylacetylene

Doi:10.1021/om010924a
(2002)
Doi:10.1002/macp.1973.021720103
(1973)

Article Doi