Diastereoselective synthesis of chiral clusters from the reaction of chiral (propargyl alcohol)Co2(CO)6 with triphenylphosphine

DOI: 10.1021/om00104a044

Source and publish data:

Organometallics p. 554 - 556 (1989)

Update date:2022-08-05

Topics:

Authors:

Bradley, David H.

Khan, Masood A.

Nicholas, Kenneth M.

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Article abstract of DOI:10.1021/om00104a044

Dicobalt hexacarbonyl complexes of chiral (racemic) propargylic alcohols 1 react with PPh₃ to form the diastereomeric complexes [R¹C≡CCH(OH)R²]Co₂-(CO) ₅PPh₃ (2) with diastereomeric excesse

Full text of DOI:10.1021/om00104a044

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