Journal of Physical Chemistry p. 5186 - 5190 (1991)
Update date:2022-08-05
Topics:
Siuzdak, G.
North, S.
BelBruno, J. J.
The phenoxy cation has been generated in polar and nonpolar solutions by two-photon ionization of phenol by using 2.5-ns pulses of 266 nm light.The ions have been characterized by pulsed conductivity (ion mobility) measurements and transient absorption spectroscopy with λmax = 290 - 300 nm and an estimated extinction coefficient of 1300 M-1 cm-1.The involvement of the phenoxy ion in ion-molecule chemistry with either neutral solute or solvent molecules has been observed.The kinetics of these processes as well as a proposed reaction mechanism are presented.
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