Polyhedron (2021)
Update date:2022-09-26
Topics:
El-bendary, Mohamed M.
Saleh, Tamer S.
Al-Bogami, Abdullah S.
The complex [Pd(paOH)2].2Cl (1) was synthesized by the self-assembly method with palladium chloride and pyridine-2-carbaldehyde-oxime (paOH) in aqueous acetonitrile solution under ambient conditions. Complex 1 was fully characterized by FT-IR, UV–vis and NMR spectroscopic techniques, as well as elemental analysis. The single crystal X-ray structure of complex 1 indicates that the Pd(II) ion is bonded to four nitrogen atoms from two pyridine-2-carbaldehyde-oxime ligands. The molecular geometry of the Pd(II) ion in complex 1 is distorted square-planar with a trans geometry and with two free chloride ions. Using an MTT assay, the anticancer activities of the palladium complex 1 were studied with respect to human breast cancer (MCF-7) and hepatocellular carcinoma (HePG-2) cell lines. The data obtained show that complex 1 displays strong activity towards the viability and the growth of the cancer cell lines MCF-7 and HepG2. Additionally, complex 1 exhibits excellent catalytic activity for the Heck cross-coupling reaction with water as the solvent under ultrasound irradiation. Ultrasound irradiation not only enhanced the rate and the yield of the reaction, but also promoted the in situ generation of a well-dispersed zero-valent Pd-colloidal species as the active catalyst from complex 1. Finally, the luminescence spectrum of complex 1 is discussed.
View MoreShiJiaZhuang Dowell Chemical Co.,Ltd.
website:http://www.dowechem.com
Contact:+86-13463963265
Address:Xiyangling village, high tech Zone, Shijiazhuang,Hebei, China
Contact:86-898-65311214
Address:Room 102, BLDG. 68 Jiangnan City, No. 66 Heping Road,Haikou, Hainan, China
Zhengzhou Xinlian Chemical Tech Co. ,Ltd
Contact:0371-65771781 021-52042910
Address:H Part, Building I, No. 700 Gonglu Road, Pudong New Area, Shanghai
Nanjing Chemlin Chemical Co., Ltd.
website:http://www.echemlin.cn
Contact:+86-25-83697070
Address:Rm.902 Longyin Plaza, No. 217 Zhongshan Rd.(N) Nanjing 210009,China
Skyrun Industrial Co.,Ltd(expird)
website:http://www.chinaskyrun.com
Contact:0086-576-84610586
Address:Chemical Development Zone
Doi:10.1021/ja01148a516
(1951)Doi:10.1080/10426500600919975
(2007)Doi:10.1016/S0968-0896(99)00291-6
(2000)Doi:10.1016/S0960-894X(98)00724-0
(1999)Doi:10.1248/cpb.35.4993
(1987)Doi:10.1016/S0040-4039(99)01285-X
(1999)