Method for Direct Synthesis of α-Cyanomethyl-β-dicarbonyl Compounds with Acetonitrile and 1,3-Dicarbonyls

DOI: 10.1021/acs.orglett.6b01871

Source and publish data:

Organic Letters p. 4151 - 4153 (2016)

Update date:2022-08-04

Topics:

Authors:

Wang, Chenyang

Li, Yabo

Gong, Ming

Wu, Qi Wu, Qi

Zhang, Jianye

Kim, Jung Keun

Huang, Mengmeng

Wu, Yangjie

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Article abstract of DOI:10.1021/acs.orglett.6b01871

A novel and efficient method for the synthesis of α-cyanomethyl-β-dicarbonyls in moderate to excellent yields is developed by using inactive CH₃CN and simple 1,3-dicarbonyls. A radical mechanism is proposed under the ESI-MS (electrospray ioniza

Full text of DOI:10.1021/acs.orglett.6b01871

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