Journal of Organic Chemistry p. 5935 - 5936 (1990)
Update date:2022-08-03
Topics:
Sawamura, Masaya
Hamashima, Hitoshi
Ito, Yoshihiko
The asymmetric aldol reaction of tosylmethyl isocyanide and aldehydes in the presence of 1 mol percent of chiral silver(I) catalysts gave optically active 5-alkyl-4-tosyl-2-oxazolines (up to 86percent ee), which were converted to optically active α-alkyl-β-(N-methylamino)ethanols by LiAlH4 reduction.
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