Direct Formation of the Steroid Nucleus by a Biomimetic Cyclization

DOI: 10.1021/ja00521a057

Source and publish data:

Journal of the American Chemical Society p. 352 - 359 (1980)

Update date:2022-08-03

Topics:

Authors:

Johnson, William S.

McCarry, Brian E.

Markezich, R. L.

Boots, Sharon G.

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Article abstract of DOI:10.1021/ja00521a057

The aim of this study was to synthesize the trienynol 3 and to study its cyclization.The substrate was synthesized by a convergent route, the key step being the stereoselective Wittig-Schlosser condensation of the known aldehyde 19 with the phosphorane 18

Full text of DOI:10.1021/ja00521a057

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