Direct Formation of the Steroid Nucleus by a Biomimetic Cyclization

DOI: 10.1021/ja00521a057

Source and publish data:

Journal of the American Chemical Society p. 352 - 359 (1980)

Update date:2022-08-03

Topics:

Authors:

Johnson, William S.

McCarry, Brian E.

Markezich, R. L.

Boots, Sharon G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00521a057

The aim of this study was to synthesize the trienynol 3 and to study its cyclization.The substrate was synthesized by a convergent route, the key step being the stereoselective Wittig-Schlosser condensation of the known aldehyde 19 with the phosphorane 18

Full text of DOI:10.1021/ja00521a057

Products guided by the article

Product name:methyl 2-carbomethoxy-3-(2-methyl-4-oxo-2-cyclohexenyl)propionate

Cas No:42723-26-2

R&D Labs maybe for 42723-26-2

Suns Chemical Sdn Bhd

Contact:0086 371 65711996

Address:Jalan 4/3, Kawasan Perindustrian Serendah, 48000 Rawang,
ZHEJIANG NHU COMPANY LTD.

Contact:86-575-86132822，86-575-86085355

Address:No.418 Dadao West Road,Qixing Street,Xinchang, Zhejiang Province, China.
Shandong Xingshun New Material Co., Ltd.

website:http://www.sd-xingshun.com

Contact:+86-519-86461196

Address:Middle of Luhua East Road, Dingtao District
ClickChem Technology Co., Limited

Contact:+86-0310-6519966/0531-52893837

Address:No.750 Shunhua Road, High-Tech Zone, Jinan city, Shandong China
Suzhou HeChuang Chemical Co.,Ltd.

Contact:+86-512-88800520

Address:No.9 Guanchao Rd,Changshu Advanced Materials Industy Park

Relevant to this article

Cycloaddition of nitrile imines to resin-bound enamines: A solid phase synthesis of 1,4-diarylpyrazoles

Doi:10.1039/b102913b
(2001)
Doi:10.1021/jo00961a004
(1973)
Design, synthesis, and activity evaluation of selective inhibitors of anti-apoptotic Bcl-2 proteins: The effects on the selectivity of the P1 pockets in the active sites

Doi:10.1016/j.bmcl.2016.09.061
(2016)
Novel betulin dicarboxylic acid ester derivatives as potent antiviral agents: Design, synthesis, biological evaluation, structure-activity relationship and in-silico study

Doi:10.1016/j.ejmech.2021.113738
(2021)
The stereoselective synthesis of oxetanes; exploration of a new, Mitsunobu-style procedure for the cyclisation of 1,3-diols

Doi:10.1039/b106851b
(2001)
Synthesis of oligonucleotides containing thiazole and thiazole N-oxide nucleobases

Doi:10.1021/ol017003g
(2002)

Article Doi