THE CHEMICAL BEHAVIOUR OF COBALT-STABILIZED-CARBENES HAVING A TRISUBSTITUTED SILYL OR GERMYL LIGAND. STEREOSPECIFIC FORMATION OF BENZOYLSILANES FROM THE REACTION OF ORGANOSILYL-COBALT TETRACARBONYL DERIVATIVES WITH PHENYLLITHIUM

DOI: 10.1016/S0022-328X(00)82934-4

Source and publish data:

Journal of Organometallic Chemistry p. 31 - 45 (1981)

Update date:2022-08-02

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Authors:

Cerveau, Genevieve

Colomer, Ernesto

Corriu, Robert J.P.

Young, J. Colin

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Article abstract of DOI:10.1016/S0022-328X(00)82934-4

We report the chemical behaviour of cobalt-stabilized carbenes, R3M(CO)3CoC(OEt)R', and their parent anions, R3M(CO)3CoC(O^-)R', where M = Si or Ge.The anions where M = Si, R' = Ph decompose thermally into the corresponding benzoylsilanes; when the silicon atom is chiral (R3 = MePh-1-Np) optically active R3SiCOPh is obtained with complete retention of configuration.

Full text of DOI:10.1016/S0022-328X(00)82934-4

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