THE CHEMICAL BEHAVIOUR OF COBALT-STABILIZED-CARBENES HAVING A TRISUBSTITUTED SILYL OR GERMYL LIGAND. STEREOSPECIFIC FORMATION OF BENZOYLSILANES FROM THE REACTION OF ORGANOSILYL-COBALT TETRACARBONYL DERIVATIVES WITH PHENYLLITHIUM

DOI: 10.1016/S0022-328X(00)82934-4

Source and publish data:

Journal of Organometallic Chemistry p. 31 - 45 (1981)

Update date:2022-08-02

Topics:

Authors:

Cerveau, Genevieve

Colomer, Ernesto

Corriu, Robert J.P.

Young, J. Colin

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0022-328X(00)82934-4

We report the chemical behaviour of cobalt-stabilized carbenes, R3M(CO)3CoC(OEt)R', and their parent anions, R3M(CO)3CoC(O^-)R', where M = Si or Ge.The anions where M = Si, R' = Ph decompose thermally into the corresponding benzoylsilanes; when the silicon atom is chiral (R3 = MePh-1-Np) optically active R3SiCOPh is obtained with complete retention of configuration.

Full text of DOI:10.1016/S0022-328X(00)82934-4

Products guided by the article

Product name:CoGe(C₆H₅)3P(OC₆H₅)3(CO)3

Cas No:42989-54-8

R&D Labs maybe for 42989-54-8

Accendatech Co., LTD

Contact:+86-22-83718541

Address:32th Floor, Rongqiao Center Intersection of Changjiang Road and Nankai Six Road Nankai District Tianjin 300102, China
Zhejiang Chemicals Import & Export Corporation (ZHECHEM)

Contact:+86-571-87046953

Address:No. 37, Qingchun Road
Jiangxi Hessence Chemicals Co., Ltd.

Contact:+86 796 3511924

Address:Chengxi Industrial Park, Jishui County, Jiangxi Province 331600 China.
GN chemicals co.,ltd

Contact:86 311 85902108 / 85902109

Address:room 1001-1005 ,huanghe Road ,shijiazhuang ,China
Hangzhou Sartort Biopharma Co., Ltd

website:http://www.sartort.com

Contact:86-571-87039693

Address:No. 57, Tech Park Road, Hangzhou, Zhejiang, China

Relevant to this article

Synthesis, characterization, and spectroscopy of 4,7,12,15-[2.2]paracyclophane containing donor and acceptor groups: Impact of substitution patterns on through-space charge transfer

Doi:10.1021/ja0121383
(2002)
Extending synthetic access to proteins with a removable acyl transfer auxiliary

Doi:10.1021/ja016731w
(2002)
Stereoselective reactions of optically active derivatives of α-methylbenzylaminophosphine

Doi:10.1023/B:RUGC.0000031849.78207.1c
(2004)
Synthesis, physicochemical and anticonvulsant properties of N-benzyl and N-aminophenyl derivatives of 2-azaspiro[4.4]nonane and [4.5]decane-1,3-dione. Part I

Doi:10.1016/j.farmac.2005.05.006
(2005)
Mixed chloride-phosphine complexes of the dirhenium core - 9. The first mixed monodentate phosphine complex, 1,2,7,8-Re₂Cl₄(PMe₂Ph)₃(PEt ₂H)

Doi:10.1016/S0020-1693(01)00740-X
(2002)
Green organometallic chemistry: CpFe⁺ -induced amination of chloroarenes in water

Doi:10.1016/S0022-328X(01)01121-4
(2002)

Article Doi