THERMAL (1,3)-ALLYLIC REARRANGEMENTS IN SULFOXIDES AND SULFONES

DOI: 10.1016/S0040-4039(00)87318-9

Source and publish data:

Tetrahedron Letters p. 2269 - 2272 (1982)

Update date:2022-07-30

Topics:

Authors:

Baechler, Raymond D.

Bentley, Pamela

Deuring, Lisa

Fisk, Susan

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Article abstract of DOI:10.1016/S0040-4039(00)87318-9

Rates and activation parameters for thermal (1,3)-allylic rearrangement have been determined for the systems β-methylallyl phenyl sulfoxide (2) and the corresponding sulfone (3), with evidence presented for a dissociative reaction mechanism.

Full text of DOI:10.1016/S0040-4039(00)87318-9

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