Electron-transfer Reactivity of the 2E Excited State of trans-Diammine(1,4,8,11-tetraazacyclotetradecane)chromium(III)

DOI: 10.1039/c39900001646

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Journal of the Chemical Society. Chemical communications p. 1646 - 1647 (1990)

Update date:2022-07-29

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Authors:

Bakac, Andreja

Espenson, James H.

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Article abstract of DOI:10.1039/c39900001646

Methyl viologen radical cation reduces the ²E excited state of trans-Cr(<14>aneN4)(NH3)2³⁺ in acidic solutions to yield a novel chromium(II) macrocycle, trans-Cr(<14>aneN4)(H2O)2²⁺, as a final product.

Full text of DOI:10.1039/c39900001646

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