Tetrahedron Letters p. 8877 - 8880 (2005)
Update date:2022-09-26
Topics:
Barberis, Claude
Gordon, Thomas D.
Thomas, Christine
Zhang, Xiaolei
Cusack, Kevin P.
Over the past few years, the use of palladium-catalyzed aromatic carbon-nitrogen bond forming reactions by the cross-coupling of aryl halides or triflates and amines has become a useful synthetic tool. Herein, we describe a copper(I) catalyst system that allows efficient synthesis of functionalized indoles and pyrrolo[2,3-c]pyridines. This method takes advantage of amino acid promoted copper coupling of amines with aryl halides, in particular, the use of the CuI/l-proline catalyst system.
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