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Green Chemistry
Page 8 of 10
DOI: 10.1039/C7GC00722A
ARTICLE
Although this study has focused in beta-glycosylation and the
Journal Name
Wang, J. Supercrit. Fluids, 2009, 49, 377; asymmetric Diels-
Alder reactions: S. Fukuzawa, K. Metoki, S. Esumi,
Tetrahedron, 2003, 59, 10445; olefin metathesis: M. Selva, A.
Perosa, M. Fabris, P. Canton, Green Chem. 2009, 11, 229; F.
Michalek, D. Mädge, J. Rühe, W. Bannwarth, Eur. J. Org.
Chem. 2006, 577.; A. Fürstner, L. Ackermann, K. Beck, H.
Hori, D. Koch, K. Langemann, M. Liebl, Ch. Six, W. Leitner, J.
Am. Chem. Soc. 2001, 123, 9000; oxidation of alcohols: R.
Ciriminna, P. Hesemann, J. J. E. Moreau, M. Carraro, S.
Campestrini, M. Pagliaro, Chem. Eur. J. 2006, 12, 5220; M. E.
González-Núñez, R. Mello, A. Olmos, R. Acerete, G. Asensio,
J. Org. Chem. 2006, 71, 1039; formation of esters: M.
strongly solvent-dependent formation of alpha-glycosides may be
anticipated to be more challenging, this reaction protocol is a proof
of concept that glycosylation can become a green process.
Acknowledgements
We are indebted to Dr. Anna M. Masdeu-Bultó (URV) for her kind
disposition to share her pressure facilities with us. We gratefully
acknowledge Prof Walter Leitner at the RWTH Aachen University as
well as Prof M. Elena González-Nuñez at the Universitat de València
for their helpful discussions. Financial support by the Ministerio de
Economia y Competividad, Spain (CTQ2014-58664-R and RYC-2015-
17705) and the European Regional Development Fund are gratefully
acknowledged. A.C. thanks URV for a predoctoral fellowship. O.B. is
a Ramón y Cajal Fellow.
Rezayat, H. S. Ghaziaskar, Green Chem. 2009, 11, 710
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