ABSOLUTE RATE CONSTANTS FOR THE ADDITIONS OF HALOPHENYLCARBENES TO ALKENES; A REACTIVITY-SELECTIVITY RELATION

DOI: 10.1016/S0040-4039(00)87856-9

Source and publish data:

Tetrahedron Letters p. 5313 - 5316 (1983)

Update date:2022-08-03

Topics:

Authors:

Cox, D. Phillip

Gould, Ian R.

Hacker, Nigel P.

Moss, Robert A.

Turro, Nicholas J.

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Article abstract of DOI:10.1016/S0040-4039(00)87856-9

The absolute rate constants determined for the additions of FCPh, ClCPh, and BrCPh to Me2C=CMe2, Me2C=CHMe, trans-MeCH=CHEt, and n-BuCH=CH2, appear to follow a reactivity/selectivity pattern of the "normal" (inverse) type.

Full text of DOI:10.1016/S0040-4039(00)87856-9

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