Journal of Organic Chemistry p. 2871 - 2875 (1984)
Update date:2022-08-04
Topics: Reduction Disproportionation Benzophenone Benzhydrol Hydrocarbon solvent
Choi, Chol-yoo
Stock, Leon M.
The reduction of benzophenone by hydrogen donor molecules such as tetralin and dihydroanthracene to give diphenylmethane was investigated in the temperature range 300-400 deg C.Several lines of evidence indicate that the reaction occurs in three distinct stages.The first stage is a radical process which gives benzhydrol.In the second stage, this intermediate undergoes an SN reaction to produce water and bis(diphenylmethyl) ether.The ether disproportionates in a readily initiated, free radical chain reaction to give diphenylmethane and benzophenone.
View MoreContact:0086-0573-85287218
Address:Room 301, Unit 2, Building 3, Alley 94, East Renmin Road, Pinghu City, Zhejiang Province, China
Shanghai agrotree chemical co.,ltd.
Contact:+86-21-50117563
Address:Room 8A,liangfeng building,No.8 dongfang RD.pudong,shanghai,China
Chemsigma International Co.,Ltd.
website:http://www.chemsigma.com
Contact:86-025-58748998
Address:Rm.705, 15th Building,Rd.Xinke II
Taixing Shenfeng Chemical Co., Ltd.
Contact:+86-523-87117033, 87117666
Address:4# Yinsanlu, Huangqiao town, Taixing, Jiangsu, China.
website:http://www.oceanchem-group.com
Contact:86-536-8596048
Address:9th floor,Building B future Plaza, No.88.Fenghuang Street,Weifang,Shandong,China
Doi:10.1016/j.bmcl.2006.04.079
(2006)Doi:10.1016/j.tetlet.2004.01.048
(2004)Doi:10.1016/S0040-4039(01)82346-7
(1974)Doi:10.1007/BF00776986
()Doi:10.1007/BF00959743
(1991)Doi:10.1039/c3pp50385b
(2014)