Novel sulfinyl imine ligands for asymmetric catalysis

DOI: 10.1021/ol027468m

Source and publish data:

Organic Letters p. 545 - 548 (2003)

Update date:2022-08-03

Topics:

Authors:

Schenkel, Laurie B.

Ellman, Jonathan A.

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Article abstract of DOI:10.1021/ol027468m

(Matrix presented) A novel class of P,N-sulfinyl imine ligands has been prepared that incorporates chirality solely at sulfur. The Pd complex of ligand 14 catalyzes the allylic alkylation reaction with high enantioselectivity (94%), and the first crystal structure of a Pd-bound sulfinyl imine provides insight into binding mode and origins of stereoselectivity.

Full text of DOI:10.1021/ol027468m

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